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Crystal_structure_miningHistoricalA Jahn-TellerBond LengthChemical ConceptsChemical Sciences

Bond stretch isomerism. Did this idea first surface 100 years ago?

https://doi.org/10.59350/awrbj-2cn42

Published February 9, 2016 in Henry Rzepa's Blog

Author Henry Rzepa

The phenomenon of bond stretch isomerism , two isomers of a compound differing predominantly in just one bond length, is one of those chemical concepts that wax and occasionally wane.[cite]10.1016/S1631-0748(02)01380-2[/cite] Here I explore such isomerism for the elements Ge, Sn and Pb. In one earlier post, I noted a form of bond stretch isomerism that can arise from a Jahn-Teller distortion ending in two different geometries

References

General Chemical EngineeringGeneral Chemistry

Bond-stretch isomerism: a case study of a quiet controversy

https://doi.org/10.1016/s1631-0748(02)01380-2

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Author Jay A. Labinger

Inorganic ChemistryPhysical and Theoretical Chemistry

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Author F. A. Cotton

Colloid and Surface ChemistryBiochemistryGeneral ChemistryCatalysis

THE ATOM AND THE MOLECULE.

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Colloid and Surface ChemistryBiochemistryGeneral ChemistryCatalysis

New Ferroelectrics Based on Divalent Metal Ion Alum

https://doi.org/10.1021/ja905399x

Published August 17, 2009 in Journal of the American Chemical Society

Authors Wen Zhang, Li-Zhuang Chen, Ren-Gen Xiong, Takayoshi Nakamura, Songping D. Huang

Colloid and Surface ChemistryBiochemistryGeneral ChemistryCatalysis

Synthesis and Characterization of 2,6-Trip₂H₃C₆PbPbC₆H₃-2,6-Trip₂ (Trip = C₆H₂-2,4,6-i-Pr₃): A Stable Heavier Group 14 Element Analogue of an Alkyne

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Published March 24, 2000 in Journal of the American Chemical Society

Authors Lihung Pu, Brendan Twamley, Philip P. Power

General Chemistry

Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers

https://doi.org/10.1039/c0sc00240b

Published January 1, 2010 in Chemical Science

Authors Yang Peng, Roland C. Fischer, W. Alexander Merrill, Jelena Fischer, Lihung Pu, Bobby D. Ellis, James C. Fettinger, Rolfe H. Herber, Philip P. Power

Inorganic Chemistry

Hemi- and holo-directed lead(ii) complexes in a soft ligand environment

https://doi.org/10.1039/c4dt01406e

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Structures and stereochemical activity of the lone pairs at the lead ion were investigated by synthetic, spectroscopic and structural studies of ten lead(ii) complexes with heterocyclic soft ligands. The majority of the complexes exhibited a hemi-directed environment around the lead ions.

General Earth and Planetary SciencesGeneral Environmental Science

Structural equilibria determined by attractive steric interactions. 1,6-Dialkylcyclooctatetraenes and their bond-shift and ring inversion investigated by dynamic NMR spectroscopy and molecular mechanics calculations

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Crystal StructureExperimental 3D CoordinatesCrystal SystemSpace GroupCell Parameters

CCDC 1019495: Experimental Crystal Structure Determination

https://doi.org/10.5517/cc136vy3

Published January 1, 2015

Authors Yu-Liang Shan, Wai-Leung Yim, Cheuk-Wai So

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CCDC 1035078: Experimental Crystal Structure Determination

https://doi.org/10.5517/cc13r2mk

Published January 1, 2014

Authors Takahiro Sasamori, Tomohiro Sugahara, Tomohiro Agou, Jing-Dong Guo, Shigeru Nagase, Rainer Streubel, Norihiro Tokitoh

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CCDC 180660: Experimental Crystal Structure Determination

https://doi.org/10.5517/cc61zry

Published January 1, 2002

Authors M. Stender, A.D. Phillips, R.J. Wright, P.P. Power

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CCDC 187521: Experimental Crystal Structure Determination

https://doi.org/10.5517/cc6942p

Published January 1, 2002

Authors A.D. Phillips, R.J. Wright, M.M. Olmstead, P.P. Power

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CCDC 221953: Experimental Crystal Structure Determination

https://doi.org/10.5517/cc7fysc

Published January 1, 2004

Authors Lihung Pu, A.D. Phillips, A.F. Richards, M. Stender, R.S. Simons, M.M. Olmstead, P.P. Power

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CCDC 297827: Experimental Crystal Structure Determination

https://doi.org/10.5517/cc9zxbh

Published January 1, 2006

Authors Y. Sugiyama, T. Sasamori, Y. Hosoi, Y. Furukawa, N. Takagi, S. Nagase, N. Tokitoh

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CCDC 624216: Experimental Crystal Structure Determination

https://doi.org/10.5517/ccnyk04

Published January 1, 2007

Authors R.C. Fischer, Lihung Pu, J.C. Fettinger, M.A. Brynda, P.P. Power

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CCDC 749451: Experimental Crystal Structure Determination

https://doi.org/10.5517/cct4vvm

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CCDC 771266: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwkks

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CCDC 771267: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwklt

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CCDC 771268: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwkmv

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CCDC 771269: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwknw

Published January 1, 2010

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https://doi.org/10.5517/cctwkpx

Published January 1, 2010

Authors Yang Peng, R.C. Fischer, W.A. Merrill, J. Fischer, Lihung Pu, B.D. Ellis, J.C. Fettinger, R.H. Herber, P.P. Power

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CCDC 771271: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwkqy

Published January 1, 2010

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CCDC 771272: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwkrz

Published January 1, 2010

Authors Yang Peng, R.C. Fischer, W.A. Merrill, J. Fischer, Lihung Pu, B.D. Ellis, J.C. Fettinger, R.H. Herber, P.P. Power

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CCDC 771273: Experimental Crystal Structure Determination

https://doi.org/10.5517/cctwks0

Published January 1, 2010

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https://doi.org/10.5517/cctwkt1

Published January 1, 2010

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CCDC 892555: Experimental Crystal Structure Determination

https://doi.org/10.5517/ccyys3r

Published January 1, 2012

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CCDC 892556: Experimental Crystal Structure Determination

https://doi.org/10.5517/ccyys4s

Published January 1, 2012

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CCDC 892557: Experimental Crystal Structure Determination

https://doi.org/10.5517/ccyys5t

Published January 1, 2012

Authors C. Jones, A. Sidiropoulos, N. Holzmann, G. Frenking, A. Stasch

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