Published in Henry Rzepa's Blog
Author Henry Rzepa
Following on from our first mechanistic reality check, we now need to verify how product A might arise in the mechanism shown below, starting from B . This pathway backtracks the original one in reversing the final arrow of that process (shown in red in previous post and in magenta here for the arrow in reverse), to go uphill in energy to reach the secondary (unstabilised) carbocation.